Reactions of Alkyl Isothiocyanates with Dianions of Cyclic Thioureas
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چکیده
منابع مشابه
Reactions of Oxime Dianions: Stereospecificity in Alkylation
n carbon.L However, no information on the stereochemistry of the alkylated products was ever reported. We now wish to report total stereospecificity in the formation and alkylation of the a-carbon, oxygen-dianions of aliphatic ketoximes. Treatment of acetoxime 1 with two equivalents of n-BuLi in THF at O°C for 15 minutes resulted in the formation of exclusively the x dianion 2, which upon deute...
متن کاملHPLC analysis of alkyl thioureas in an orthopaedic brace and patch testing with pure ethylbutylthiourea
متن کامل
HPLC analysis of alkyl thioureas in an orthopaedic brace and patch testing with pure ethylbutylthiourea.
Ethylbutylthiourea (EBTU) is an accelerator used in the production of chloroprene (neoprene) rubber. EBTU occurs in a mixture with diethylthiourea (DETU) and dibutylthiourea (DBTU) in the accelerator. An analytical method originally developed for analysis of zinc dithiocarbamates in rubber has been used to analyse EBTU, DETU and DBTU in a knee brace responsible for an allergic contact dermatiti...
متن کاملdetection of volatile compounds of medicinal plants with some nano-sorbents using modified or new methodologies and investigation of antioxidant activity of their methanolic extracts
in this work, a novel and fast method for direct analysis of volatile compounds (davc) of medicinal plants has been developed by holding a filament from different parts of a plant in the gc injection port. the extraction and analysis of volatile components of a small amount of plant were carried out in one-step without any sample preparation. after optimization of temperature, extraction time a...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1986
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.59.3693